Complexes of Cadmium with Ethylacetate and Acetyl acetone have been prepared and characterized by chemical analyses, molar conductivity, spectroscopic and molar conductance measurements, IR, H¹NMRspectra and C¹³NMR spectra. The IR and NMR spectral studies of these complexes (Except those Ethylacetate and Acetyl acetone) indicate that they complexes are non-hygroscopic in nature and are soluble in common organic solvents. It has been found that behaves as pentadentate ligands. The Cadmium complexes containing acetylacetonato with cadmium sulphate & ethylacetate yielded complexes assigned square planar structures. From the IR, H¹NMR spectra and C¹³NMR spectra of Cadmium complexes various parameters have been calculated.